If you upload sample application, that will be great..
Using "*" in section access doesn't mean "all values for field" but "all listed values for field within section access". If you want a user to get all information, set nothing instead the asterisk for any admin user, and as many lines as possible values for each user.
Hope that helps
Also i will suggest store section access data into the Qvd and then load into application. Use NTID not NSTID.