I have also seen that it's not possible to use a master item in another master item as I had already created the Master measure for Networkdays(Request date, approved date) renamed as "pending days", hoping to piggy back off the existing master item to create the new dimension to be something like:
if(Pending days >=2, '0-1 days', 'unknown') but it wont register the master item in the expression.
The end result is to be able to use the groupings dimension in a pie chart to show the break down via the day grouping lengths.